SEM-EDX GUIDE FOR BUYERS
Chapter 3 - Imaging and Spectroscopy Detectors
Standard Types of Detector
During operation of the SEM, the electron beam is scanned point by point over the sample. The backscattered electrons are counted in the imaging detectors. At the same time, the electron beam excites the sample to emit characteristic X-rays. By analyzing the X-ray spectrum, the elements in the sample can be determined. Three detector systems are considered standard for SEM devices:
- Backscattered electrons (BE) → material contrast
- Secondary electrons (SE) → topography contrast
- Energy dispersive X-ray spectroscopy (EDX) → elemental analysis
The following diagram shows the generation of the primary electron beam, its interaction with the sample and the arrangement of the detector systems:

Backscatter and Secondary Electrons (BE / SE)
For imaging, backscatter and secondary electron detectors have prevailed. The backscattered electrons (BE) show the element or material contrast of the sample. The heavier an element is, the brighter the area in the BE image appears. The secondary electrons (SE) originate from the surface and reflect the topography of the sample.
Note that the SEM device of your choice can integrate both BE and SE detector systems. The information content is complementary and in the practical work the consideration of both modalities is essential.
X-Ray Element Analysis (EDX)
Elemental analysis using X-ray spectroscopy (EDX) is optionally available on all SEM devices. Some manufacturers offer their own hardware and software that is fully integrated into the SEM software and thus offers a higher level of user-friendliness. Manufacturers often also install EDX systems from third-party suppliers that offer highly specialized analysis modules. In this case, the EDX is controlled via separate software, which slows down the workflow. The basic EDX analysis methods of individual measurements (point or area) as well as profiles or element mappings are generally available from all suppliers. Additional software modules (e.g. for automatic particle analysis) can be used if required.
Transmission Electrons (STEM)
Recently, scanning transmission electron microscopy (STEM) is no longer reserved for large research devices. Some tabletop SEMs and compact devices with STEM detectors offer the possibility of imaging thin sections on standardized TEM grids. This new option is particularly interesting for organic preparations and tissue sections.